環(huán)境催化與污染控制化學(xué)團(tuán)隊

學(xué)術(shù)帶頭人：唐和清

團(tuán)隊成員：

唐和清、呂康樂、張勝花、丁耀彬、雷鳴、萬震

團(tuán)隊簡介：

本團(tuán)隊一直致力于研究環(huán)境中典型污染物的賦存形態(tài)、分布規(guī)律、光化學(xué)轉(zhuǎn)化行為歸趨以及環(huán)境催化新材料及其在污染控制中的應(yīng)用，尤其在高性能環(huán)境催化材料的設(shè)計、可控制備、性能研究以及應(yīng)用等方面取得了創(chuàng)新性的研究成果。

主要研究方向：

●污染控制化學(xué)：主要包括類Fenton體系的擴(kuò)展與強(qiáng)化、微污染水體系的深度凈化、工業(yè)污染水與固廢的處置；

●多功能催化劑：重點(diǎn)研究具有強(qiáng)吸附能力的催化性雙功能材料，包括以粘土礦物、多形態(tài)碳等基質(zhì)的多功能材料；

●光催化：重點(diǎn)研究二氧化鈦及新型光催化材料的可控制備，及其降解污染物的反應(yīng)歷程和催化機(jī)理；

●分子印跡：重點(diǎn)研究分子印跡型吸附材料及其與二氧化鈦復(fù)合而成的選擇性光催化材料，開發(fā)其在環(huán)境污染控制應(yīng)用；

●環(huán)境光化學(xué)：重點(diǎn)研究地表水及大氣中持久性有機(jī)污染物的賦存形態(tài)、分布規(guī)律、光化學(xué)轉(zhuǎn)化及行為歸趨

●湖泊生態(tài)修復(fù)：重點(diǎn)研究富營養(yǎng)化湖泊的生態(tài)響應(yīng)過程、進(jìn)程、機(jī)理以及防控措施。

近期完成或正在進(jìn)行的主要研究項目：

1.國家自然科學(xué)基金面上項目，載流子自分離型光催化微界面的構(gòu)筑及其高效降解溴酚類污染物（21876209）.

2.國家自然科學(xué)基金面上項目，“C8”類全氟化合物固廢的機(jī)械化學(xué)無害化處置及資源化方法研究（21777194）.

3.國家自然科學(xué)基金面上項目，基于晶面接觸效應(yīng)構(gòu)建高效半導(dǎo)體復(fù)合光催化材料（51672312）.

4.國家自然科學(xué)基金面上項目，天然水中鄰苯二甲酸酯類塑化劑的富存與光降解機(jī)理研究(21477088).

5.國家自然科學(xué)基金面上項目，催化反應(yīng)性超級吸附體系的構(gòu)筑及其去除低暴露水平環(huán)境激素污染物的研究（21377169）.

6.國家自然科學(xué)基金面上項目，基于生物原細(xì)胞模型的凝聚層半導(dǎo)體光催化體系研究（21373275）.

7.國家自然科學(xué)基金面上項目，微界面調(diào)控增強(qiáng)全氟羧酸化學(xué)催化氧化降解的方法研究（21077037）.

8.國家自然科學(xué)基金面上項目，高能面二氧化鈦的超強(qiáng)氟效應(yīng)光催化降解惡臭有毒氣體（20977114）.

9.國家自然科學(xué)基金面上項目，人工抗體型光催化劑的合成及選擇性降解有毒污染物研究（20677019）.

10.國家自然科學(xué)基金地區(qū)項目：滇池水華優(yōu)勢藍(lán)藻的磷吸收存儲及水華消亡時殘體的磷礦化機(jī)制（51468066）.

11.國家自然科學(xué)基金青年項目，In₂O₃表面活性氫物種調(diào)控及其實現(xiàn)PBDEs光催化深度脫溴的反應(yīng)機(jī)制研究（21906184）

11.國家自然科學(xué)基金青年項目，g-C₃N₄固載的單原子分散Pd催化劑及其催化PBDEs深度還原脫溴（21707170）.

11.國家自然科學(xué)基金青年項目，自摻雜鉍基光催化劑光催化氧化及其單線態(tài)氧直接氧化協(xié)同降解PPCPs（21507168）.

12.國家自然科學(xué)基金青年項目，天然酚類抗氧化劑對果蔬表面二噻農(nóng)殺菌劑光化學(xué)轉(zhuǎn)化的影響及其機(jī)理研究(21207102).

13.國家自然科學(xué)基金青年項目，滇池水華優(yōu)勢藍(lán)藻的磷吸收存儲及水華消亡時殘體的磷礦化機(jī)制（51468066）.

13.國家863計劃項目子課題，集約養(yǎng)殖外源化學(xué)品污染控制技術(shù)（2012AA06A304）.

14.教育部“新世紀(jì)優(yōu)秀人才支持計劃”，空心納米顆粒自組裝二氧化鈦空心微球光催化空氣凈化（NCET-12-0668），2013-2015.

15.湖北省杰出青年基金，橄欖球形單晶二氧化鈦空心球的制備與光催化性能研究（2011CDA107）.

近期代表性研究論文：

1. Chao Yang, Qiuyan Tan, Qin Li, Jie Zhou*, Jiajie Fan, Bing Li, Jie Sun, Kangle Lv*, 2D/2D Ti₃C₂ MXene/g-C₃N₄ nanosheets heterojunction for high efficient CO₂ reduction photocatalyst: Dual effects of urea, Appl. Catal. B: Environ. 2020, 268, 118738. （ESI高被引）

2. Xiaofang Li, Zhao Hu, Qin Li, Ming Lei, Jiajie Fan, Sónia A.C. Carabineiro, Yi Liu*, Kangle Lv*, Three in one: atomically dispersed Na boosting the photoreactivity of carbon nitride towards NO oxidation, Chem. Commun. 2020, DOI: 10.1039/d0cc05948j.

3. Zhao Hu, Xiaofang Li*, Sushu Zhang, Qin Li, Jiajie Fan, Xianlin Qu, Kangle Lv*, Fe₁/TiO₂ hollow microspheres: Fe and Ti dual active sites boosting the photocatalytic oxidation of NO, Small 2020, 2004583.

4. Zhao Hu, Chao Yang, Kangle Lv*, Qin Li, Xiaofang Li, Jiajie Fan, Single atomic Au induced dramatic promotion of the photocatalytic activity of TiO₂ hollow microspheres, Chem. Commun.2020, 56, 1745-1748.

5. Ming Lei, Zhiying Wang, Yao Tang, Huimin Wang, Lihua Zhu*, Heqing Tang*, Peculiar and full debromination of tetrabromodiphenyl ether on Pd/TiO₂: a competing route through hydro-debromination and coupling-debromination, Appl. Catal. B: Environ., 2020, 275, 119093.

6. Ming Lei, Zhiying Wang, Lihua Zhu*, Wenshan Nie, Heqing Tang*, Complete debromination of 2,2’,4,4’-tetrabromodiphenyl ether by visible-light photocatalysis on g-C₃N₄ supported Pd, Appl. Catal. B: Environ., 2020, 261, 118236.

7. Shun Guo, Lihua Zhu*, Tetsuro Majima, Ming Lei, Heqing Tang*, Reductive debromination of polybrominated diphenyl ethers: dependence on Br number of the Br-rich phenyl ring. Environ. Sci. Technol., 2019, 53, 8, 4433-4439.

8. Nan Wang, Hanqing Lv, Yuqi Zhou, Lihua Zhu*, Yue Hu, Tetsuro Majima, Heqing Tang*, Complete defluorination and mineralization of perfluorooctanoic acid by a mechanochemical method using alumina and persulfate. Environ. Sci. Technol., 2019, 53, 14, 8302-8313.

9. Jin Cao, Wenshan Nie, Long Huang, Yaobin Ding*, Kangle Lv, Heqing Tang*, Photocatalytic activation of sulfite by nitrogen vacancy modified graphitic carbon nitride for efficient degradation of carbamazepine, Appl. Catal. B: Environ., 2019, 241, 18-27. （ESI高被引）

10. Jinshui Cheng, Zhao Hu, Qin Li, Xiaofang Li*, Shun Fang, Xiaofeng Wu, Mei Li, Yaobin Ding, Bing Liu, Changjun Yang, Lili Wen, Yi Liu, Kangle Lv*, Fabrication of high photoreactive carbon nitride nanosheets by polymerization of amidinourea for hydrogen production, Appl. Catal. B: Environ.2019, 245, 197-206.

11. Chao Yang, Qin Li*, Yang Xia, Kangle Lv*, Mei Li, Enhanced visible-light photocatalytic CO₂ reduction performance of Znln₂S₄ microspheres by using CeO₂ as cocatalyst, Appl. Surf. Sci.2019, 464, 388-395. （ESI高被引）

12. Wenshan Nie, Qihang Mao, Yaobin Ding*, Yue Hu, Heqing Tang*, Highly efficient catalysis of chalcopyrite with surface bonded ferrous species for activation of peroxymonosulfate toward degradation of bisphenol A: A mechanism study. J. Hazard. Mater., 2019, 364, 59-68. （ESI高被引）

13. Jingsha. Xu, Chunrong. Jia, Jun. He*, Honghui. Xu, Yuting. Tang, Ddongsheng. Ji, Huan. Yu, Hang. Xiao, Chengjun Wang*, Biomass burning and fungal spores as sources of fine aerosols in Yangtze River Delta, China-using multiple organic tracers to understand variability, correlations and origins. Environmental Pollution, 2019, 251, 155-165.

14. Yuhan Li, Xiaofeng Wu, Wingkei Ho*, Kangle Lv*, Qin Li, Mei Li, Shuncheng Lee, Graphene-induced formation of visible-light-responsive SnO₂-Zn₂SnO₄ Z-scheme photocatalyst with surface vacancy for the enhanced photoreactivity towards NO and acetone oxidation, Chem. Eng. J.2018, 336, 200-210. （ESI高被引）

15. Ming Lei, Shun Guo, Zhiying Wang, Lihua Zhu*,Heqing Tang*, Ultrarapid and deep debromination of tetrabromodiphenyl ether over noble-metal-free Cu/TiO₂ nanocomposites under mild conditions. Environ. Sci. Technol., 2018, 52, 20, 11743-11751.

16. Yuhan Li, Kangle Lv*, Wingkei Ho*, Fan Dong, Xiaofeng Wu, Yang Xia, Hybridization of rutile TiO₂ (rTiO₂) with g-C₃N₄ quantum dots (CN QDs): An efficient visible-light-driven Z-scheme hybridized photocatalyst. Appl. Catal. B: Environ.2017, 202, 611-619. （ESI高被引）

17.Yaobin Ding, Guangli Zhang, Xueru Wang, Lihua Zhu*, Heqing Tang*, Chemical and photocatalytic oxidative degradation of carbamazepine by using metastable Bi³⁺ self-doped NaBiO₃ nanosheets as a bifunctional material, Appl. Catal. B: Environ. 2017, 202, 528-838.

18. Ruiwen Yang, Jinghua Cai, Kangle Lv*, Xiaofeng Wu, Wenguang Wang, Zhihua Xu, Mei Li*, Qin Li, Weiqing Xu, Fabrication of TiO₂ Hollow Microspheres Assembly from Nanosheets (TiO₂-HMSs-NSs) with Enhanced Photoelectric Conversion Efficiency in DSSCs and Photocatalytic Activity. Appl. Catal. B: Environ. 2017,210, 184-193.

19. Kangle Lv*, Xiaojia Guo, Xiaofeng Wu, Qin Li, Wingkei Ho*, Mei Li, Hengpeng Ye, Dongyun Du, Photocatalytic selective oxidation of phenol to produce dihydroxybenzenes in a TiO₂/UV system: Hydroxyl radical versus hole. Appl. Catal. B: Environ. 2016, 199, 405-411.

20. Shun Fang, Yang Xia, Kangle Lv*, Qin Li, Jie Sun, Mei Li*, Effect of carbon-dots modification on the structure and photocatalytic activity of g-C₃N₄. Appl. Catal. B: Environ. 2016, 185, 225-232.

21. Shun Fang, Yang Xia, Kangle Lv*, Qin Li, Jie Sun, Mei Li*, Effect of carbon-dots modification on the structure and photocatalytic activity of g-C₃N₄. Appl. Catal. B: Environ. 2016, 185, 225-232. （ESI高被引）

22. Ze’ai Huang, Qiong Sun, Kangle Lv*, Zehui Zhang, Mei Li, Bing Li, Effect of contact interface between TiO₂ and g-C₃N₄ on the photoreactivity of g-C₃N₄/TiO₂ photocatalyst: (001) vs (101) facets of TiO₂. Appl. Catal. B: Environ.2015, 164, 420-427. （ESI高被引）

23. Xiaobo Wang, Yanlei Qin, Lihua Zhu, and Heqing Tang*, Nitrogen-Doped Reduced Graphene Oxide as a Bifunctional Material for Removing Bisphenols: Synergistic Effect between Adsorption and Catalysis, Environ. Sci. Technol.2015, 49, 11, 6855–6864. （ESI高被引）

24. Yaobin Ding, Fan Yang, Lihua Zhu*, Nan Wang, Heqing Tang*, Bi³⁺ self doped NaBiO₃ nanosheets: Facile controlled synthesis and enhanced visible light photocatalytic activity, Appl. Catal. B: Environ. 2015, 164, 151-158.