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張華老師簡介
張華老師簡介

姓名張華

職稱:教授

單位:中南民族大學化學與材料科學學院

學科專業:有機化學

研究方向:有機硼化學,有機合成,金屬有機,均相催化

學者簡介:

 張華,博士,教授。2008.6(本科)、2013.6(博士)畢業于武漢大學。2013.8-2015.12于日本名古屋大學(JSPS)和美國加州大學爾灣分校從事博士后研究。2016.3-2019.11于南昌大學開展獨立科研工作(特聘教授,博士生導師)。2019.12至今于中南民族大學開展獨立科研工作(教授,碩士生導師)。主持國家自然科學基金青年項目(2017-2019)與面上項目(2023-2026)。榮獲2020年度Thieme Chemistry Journals Award。受邀擔任Science等國際知名期刊的審稿人。課題組與多個知名高校課題組(復旦大學、武漢大學、浙江大學、南京大學、南方科技大學、湖南大學等)有緊密聯系,表現優異同學有機會赴上述高校聯合培養。課題組有多名碩士畢業生在武漢大學、中山大學、南方科技大學、湖南大學、南昌大學等高校攻讀博士學位或博士畢業。

聯系方式:huazhang@scuec.edu.cn

獨立后工作:

1. Y. Liang, C. Du, C. Dong, J. Cao, Y. Xu, H. Zhang*. Metal-Free ortho C–H Borylation of benzamides. Org. Lett. 2025, 27, in revision.

2. S. Tang, S. Wang, H. Zhang*. Visible-Light Induced Radical Hydroaroylation of Vinyl Boronic Ester with Aroyl Chlorides to Access β-Boryl Ketones, Org. Lett. 2025, 27, in revision.

3. B. Zhan, L.-Q. Ren, J. Zhao, H. Zhang*, C. He*. Catalytic asymmetric C-N cross-coupling towards boron-stereogenic 3-amino-BODIPYs, Nature Commun. 2025, 16, 438.

4. S. Tang, Z. Wang, M. Zhu, X. Zhao*, X. Hu*, H. Zhang*. Synthesis of organoboron compounds via heterogeneous C-H and C-X borylation. Chin. Chem. Lett. 2025, 36, 110503.

5. B. Zhan, J. Lv, J. Wu, H. Zhang*, Synthesis of C5-boryl indoles via a borane-catalyzed borylation/hydride transfer cascade, Chem Catal. 2024, 4, 100975.

6. J. Lv, Y. Liang, Y. Ouyang, H. Zhang*. Metal-Free ortho C?H Borylation of Thiobenzamides, Org. Lett. 2024, 26, 3709–3714.

7. S. Tang, W. Xu#, H. Zhang*. Transition-metal-free photochemical reductive denitration of nitroarenes. Chem. Commun. 2024, 60, 13754–13757.#本科生共同第一作者)

8. L. Du, B. Zhang, S. Ji, H. Cai*, H. Zhang*. Electrochemical borylation of nitroarenes. Sci. China. Chem. 2023, 66, 534–539.

9. C. Yin, S. Tang, J. Mei, X. Hu*, H. Zhang*. Electrochemical synthesis and transformation of organoboron compounds. Org. Chem. Front. 2023, 10, 3361–3377.

10. C. Yin, L. Luo, H. Zhang*. Iodine-Catalyzed Borylation of Benzylic Alcohols. Org. Lett. 2023, 25, 1701-1705. (Highlighted by “OPR&D”, see Org. Process Res. Dev. 2023, 27, 811–821)

11. L. Luo, S. Tang, J. Wu, S. Jin*, H. Zhang*. Transition Metal-Free Aromatic C–H, C–N, C–S and C–O Borylation. Chem. Rec. 2023, 23, e202300023. (Invited Review)

12. L. Du, H. Zhang*. Photochemical and Electrochemical Borylation Involving Aryl and Alkyl Compounds. Chin. J. Org. Chem. 2023, 43, 1726–1741. (Invited Review)

13. X. Li, Z. Wan, X. Hu*, H. Zhang*. Photoinduced aerobic C–S borylation of aryl sulfides. Org. Chem. Front. 2022, 9, 3034–3038.

14. S. Ji, S. Qin, C. Yin, L. Luo, H. Zhang*, Unreactive C?N Bond Activation of Anilines via Photoinduced Aerobic Borylation, Org. Lett. 2022, 24, 64–68. (Highlighted by “OPR&D”, see Org. Process Res. Dev. 2022, 26, 3181–3189)

15. L. Du, L. Sun, H. Zhang*, Photochemical and electrochemical C–N borylation of arylhydrazines, Chem. Commun. 2022, 58, 1716–1719.

16. L. Wang, Q. Zhong, Y. Zou, Y. Yin, A. Wu, Q. Chen, K. Zhang, J. Jiang, M. Zhao, H. Zhang*, Carbon-carbon bond activation by B(OMe)3/B2pin2-mediated fragmentation borylation, Chem. Sci. 2021, 12, 15104–15109.

17. Y. Zou, B. Zhang, L. Wang, H. Zhang*, Benzoic Acid-Promoted C2?H Borylation of Indoles with Pinacolborane, Org. Lett. 2021, 23, 2821–2825.

18. B. Zhang, Y. Zou, L. Wang, H. Zhang*, Zinc catalysed C3–H borylation of indoles and 1,1-diboration of terminal alkynes, Chem. Commun. 2021, 57, 11185–11188.

19. H. Zhang*, L. Wang, Metal-Free Catalytic Aromatic C–H Borylation, Synlett, 2020, 31, 1857–1861. (Invited Synpacts article)

20. S. Qin, T. Li, M. Zhang, H. Liu, X. Yang, N. Rong, J. Jiang, Y. Wang, H. Zhang*, W. Yang*, Catalyst-free Synthesis of Biodiesel Precursors from Biomass-based Furfuryl Alcohols in the Presence of H2O and Air, Green Chem. 2019, 21, 63266334.

21. Q. Zhong, S. Qin, Y. Yin, J. Hu, H. Zhang*, B(III)-Catalyzed C2-selective C–H Borylation of Heteroarenes, Angew. Chem. Int. Ed. 2018, 57, 1489114895. (Top Downloaded Paper 2018-2019 in Wiley)

22. Q. Chen, A. Wu, S. Qin, M. Zeng, Z. Le*, Z. Yan*, H. Zhang*, Ni-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Unactivated Phenol and Phenylmethanol Derivatives, Adv. Synth. Catal. 2018, 360, 32393244.

23. A. Wu, Q. Chen, W. Liu*, L. You, Y. Fu, H. Zhang*, Transition-metal-free Arylation of Benzoxazoles with Aryl Nitriles, Org. Chem. Front. 2018, 5, 18111814.

24. Y. Yin, X. Yue, Q. Zhong, H. Jiang, R. Bai*, Y. Lan*, H. Zhang*, Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluroides and Corresponding Coupling with Oxazoles, Adv. Synth. Catal. 2018, 360, 16391643.

25. Z. Zeng, T. Zhang, X. Yue, H. Zhang*, R. Bai*, Y. Lan*, Mechanism investigation for anoin-assisted nickel catalyzed C–F bond functionalization reaction: a DFT study, Sci. Sin. Chim. 2018, 48, 736742.

26. W. Liu*, L. Xu, G. Lu, H. Zhang*, Selective Partial Hydrogenation of Methyl Linoleate Using Highly Active Palladium Nanoparticles in Polyethylene Glycol, ACS. Sustainable. Chem. Eng. 2017, 5, 13681375.

獨立前工作:

1. H. Zhang, R. Shi, P. Gan, C. Liu, A. Ding, Q. Wang, A. Lei*, Palladium-Catalyzed Oxidative Double C–H Functionalization/Carbonylation for the Synthesis of Xanthones, Angew. Chem. Int. Ed. 2012, 51, 5204. (“Hot Paper”)

2. H. Zhang, R. Shi, A. Ding, L. Lu, B. Chen, A. Lei*, Transition-Metal-Free Alkoxycarbonylation of Aryl Halides, Angew. Chem. Int. Ed. 2012, 51, 12542.

3. R. Shi[1], H. Zhang[1], L. Lu, P. Gan, Y. Sha, H. Zhang, Q. Liu, M. Beller*, A. Lei*, (E)-a,b-unsaturated amides from tertiary amines, olefins and CO via Pd/Cu-catalyzed aerobic oxidative N-dealkylation, Chem. Commun. 2015, 51, 3247.

4. H. Zhang, S. Hagihara, K. Itami*, Making Dimethylamino a Transformable Directing Group by Nickel-Catalyzed C–N Borylation, Chem. Eur. J. 2015, 21, 16796.

5. H. Zhang, D. Liu, C. Chen, C. Liu, A. Lei*, Palladium-Catalyzed Regioselective Aerobic Oxidative C–H/N–H Carbonylation of Heteroarenes under Base-Free Conditions, Chem. Eur. J. 2011, 17, 9581.

6. H. Zhang, S. Hagihara, K. Itami*, Aromatic C–H Borylation by Nickel Catalysis, Chem. Lett. 2015, 44, 779.

7. Y. Tsuchiya*, M. Yoshimura, Y. Sato, K. Kuwata, S. Toh, D. Holbrock-Smith, H. Zhang, P. McCourt, K. Itami, T. Kinoshita, S. Hagihara*, Probing strigolactone receptors in Striga hermonthica with fluorescence, Science 2015, 349, 864.

8. N. Uchida, K. Takahashi, R. Iwasaki, R. Yamada, M. Yoshimura, T. A Endo, S. Kimura, H. Zhang, M. Nomoto, Y. Tada, T. Kinoshita, K. Itami, S. Hagihara*, K. U Torii*, Chemical hijacking of auxin signaling with an engineered auxin-TIR1 pair, Nature Chem. Biol. 2018, 14, 299.

 


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